Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis
Résumé
Primary, secondary and tertiary alkyl radicals, formed by photocatalyzed oxidation of organosilicates, can be involved efficiently in radical carbonylation with carbon monoxide (CO), which leads to a variety of unsymmetrical ketones. This work constitutes the first example of radical carbonylation under a photooxidative regime.
Domaines
Chimie organique
Origine : Fichiers produits par l'(les) auteur(s)
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