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Article Dans Une Revue Angewandte Chemie International Edition Année : 2019

Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis

Résumé

Primary, secondary and tertiary alkyl radicals, formed by photocatalyzed oxidation of organosilicates, can be involved efficiently in radical carbonylation with carbon monoxide (CO), which leads to a variety of unsymmetrical ketones. This work constitutes the first example of radical carbonylation under a photooxidative regime.

Domaines

Chimie organique
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Dates et versions

hal-02010150 , version 1 (26-08-2019)

Identifiants

Citer

Alex Cartier, Etienne Levernier, Vincent Corcé, Takahide Fukuyama, Anne-Lise Dhimane, et al.. Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis. Angewandte Chemie International Edition, 2019, 58 (6), pp.1789-1793. ⟨10.1002/ange.201811858⟩. ⟨hal-02010150⟩
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