Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Synthesis: Journal of Synthetic Organic Chemistry Année : 2019

Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids

Résumé

The distinct reactivity of 1,6-enynes in the presence of a trinuclear metal complex activated by a carboxylic acid is presented. The triplatinum catalyst enables the cyclization of the substrate and subsequent incorporation of a nucleophile in the final product. In contrast, sequential cyclization/double bond shift occurs under analogous conditions in the presence of the corresponding tripalladium complex.

Domaines

Chimie
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Dates et versions

hal-02066113 , version 1 (13-03-2019)

Identifiants

Citer

Chiara Cecchini, Matteo Lanzi, Gianpiero Cera, Max Malacria, Giovanni Maestri. Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids. Synthesis: Journal of Synthetic Organic Chemistry, 2019, 51 (05), pp.1216-1224. ⟨10.1055/s-0037-1611653⟩. ⟨hal-02066113⟩
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