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Article Dans Une Revue Chemical Science Année : 2020

Asymmetry controlled dynamic behavior of autonomous chemiluminescent Janus microswimmers †

Résumé

Asymmetrically modified Janus microparticles are presented as autonomous light emitting swimmers. The localized dissolution of hybrid magnesium/polymer objects allows combining chemiluminescence with the spontaneous production of H 2 bubbles, and thus generating directed motion. These light-emitting microswimmers are synthesized by using a straightforward methodology based on bipolar electromilling, followed by indirect bipolar electrodeposition of an electrophoretic paint. An optimization of the experimental parameters enables in the first step the formation of well-defined isotropic or anisotropic Mg microparticles. Subsequently, they are asymmetrically modified by wireless deposition of an anodic paint. The degree of asymmetry of the resulting Janus particles can be fine-tuned, leading to a controlled directional motion due to anisotropic gas formation. This autonomous motion is coupled with the emission of bright orange light when Ru(bpy) 3 2+ and S 2 O 8 2À are present in the solution as chemiluminescent reagents. The light emission is based on an original process of interfacial redox-induced chemiluminescence, thus allowing an easy visualization of the swimmer trajectories.

Domaines

Chimie
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Dates et versions

hal-02938138 , version 1 (14-09-2020)

Identifiants

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Gerardo Salinas, Alice L. Dauphin, Silva Voci, Laurent Bouffier, Neso Sojic, et al.. Asymmetry controlled dynamic behavior of autonomous chemiluminescent Janus microswimmers †. Chemical Science, 2020, 11 (28), pp.7438-7443. ⟨10.1039/d0sc02431g⟩. ⟨hal-02938138⟩
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