A smarter approach to catalysts by design: Combining surface organometallic chemistry on oxide and metal gives selective catalysts for dehydrogenation of 2,3-dimethylbutane - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Molecular Catalysis Année : 2019

A smarter approach to catalysts by design: Combining surface organometallic chemistry on oxide and metal gives selective catalysts for dehydrogenation of 2,3-dimethylbutane

Résumé

2,3-dimethylbutane is selectively converted into 2,3-dimethylbutenes at 500°C under hydrogen or at 390°C under nitrogen in the presence of bimetallic catalysts Pt-Sn/Li-Al 2 O 3. The high stability of the catalyst along the reaction is obtained by selective modification of the Pt/Li-Al 2 O 3 catalyst using Surface Organometallic Chemistry (SOMC).
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hal-03096779 , version 1 (06-01-2021)

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Pascal Rouge, Anthony Garron, Sébastien Norsic, Cherif Larabi, Nicolas Merle, et al.. A smarter approach to catalysts by design: Combining surface organometallic chemistry on oxide and metal gives selective catalysts for dehydrogenation of 2,3-dimethylbutane. Molecular Catalysis, 2019, 471, pp.21 - 26. ⟨10.1016/j.mcat.2019.04.011⟩. ⟨hal-03096779⟩
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