Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units
Abstract
A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded pconjugated backbone has been synthesized and characterized. This promising photo-and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acceptor system. Our studies show its self-assembly resulting from aggregation via p-p stacking interaction in solution and in the solid state.
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