Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study
Résumé
Ca(NTf 2 )PF 6 , generated from commercial precursors, promotes imine hydrosilylation in high yields and is used to prepare a bioactive amine on the gram scale. The mechanistic investigations highlight an unprecedented Si–H activation by the Ca center.
Domaines
Chimie
Origine : Fichiers produits par l'(les) auteur(s)