A general model of the anodic behaviour of nickel in acidic media
Résumé
An experimental study of the anodic behaviour of nickel in acidic media is carried out by steady state polarization curves and faradaïc impedance measurements as a function of various parameters related to the electrolyte: pH, concentration and the nature of the anions. We propose several models of the electrode reaction path based on heterogenous chemical kinetic concepts. By a convenient numerical fitting method, we calculate a set of kinetic parameters which are afterwards put into the theoretical equations for dc and the impedance. By this procedure we are able to choose a general model accounting for the behaviour of nickel in a wide range of experimental conditions: active dissolution, passivity, secondary passivity and the oxidation of OH− to molecular oxygen.