Journal Articles Electrochimica Acta Year : 1976

A general model of the anodic behaviour of nickel in acidic media

A. Jouanneau
  • Function : Author
M.C. Petit
  • Function : Author

Abstract

An experimental study of the anodic behaviour of nickel in acidic media is carried out by steady state polarization curves and faradaïc impedance measurements as a function of various parameters related to the electrolyte: pH, concentration and the nature of the anions. We propose several models of the electrode reaction path based on heterogenous chemical kinetic concepts. By a convenient numerical fitting method, we calculate a set of kinetic parameters which are afterwards put into the theoretical equations for dc and the impedance. By this procedure we are able to choose a general model accounting for the behaviour of nickel in a wide range of experimental conditions: active dissolution, passivity, secondary passivity and the oxidation of OH− to molecular oxygen.

Dates and versions

hal-04817997 , version 1 (04-12-2024)

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A. Jouanneau, Michel Keddam, M.C. Petit. A general model of the anodic behaviour of nickel in acidic media. Electrochimica Acta, 1976, 21 (4), pp.287-292. ⟨10.1016/0013-4686(76)80021-7⟩. ⟨hal-04817997⟩
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