Molecular Diversity of Cyclooctatetraenes through Palladium-Catalyzed Cascade Reactions - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2018

Molecular Diversity of Cyclooctatetraenes through Palladium-Catalyzed Cascade Reactions

Résumé

We report a cascade reaction leading to fully substituted cyclooctatetraenes. This transformation likely proceeds through a double cyclocarbopalladation, a unique 8-electrocyclization and ends by either a Stille, Sonogashira or Suzuki-Miyaura cross coupling. Structural modifications of the starting material were investigated to identify their effects on the reaction and extend the structural diversity possible through this transformation.
Fichier principal
Vignette du fichier
HAL.pdf (671.86 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-02322480 , version 1 (14-02-2022)

Identifiants

Citer

Sarah Blouin, Romain Pertschi, Angèle Schoenfelder, Jean Suffert, Gaëlle Blond. Molecular Diversity of Cyclooctatetraenes through Palladium-Catalyzed Cascade Reactions. Advanced Synthesis and Catalysis, 2018, 360 (11), pp.2166-2171. ⟨10.1002/adsc.201800110⟩. ⟨hal-02322480⟩
27 Consultations
29 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More