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Journal Articles Inorganics Year : 2022

Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages

Amina Benchohra
Simon Séjourné
  • Function : Author
Antoine Labrunie
  • Function : Author
Liam Miller
  • Function : Author
Enzo Charbonneau
  • Function : Author
Magali Allain
Marc Sallé
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Sébastien Goeb
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Abstract

Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M2), afforded three chiral face-rotating stereoisomer polyhedra (M6L2). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M6L2), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.

Dates and versions

hal-03773676 , version 1 (09-09-2022)

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Amina Benchohra, Simon Séjourné, Antoine Labrunie, Liam Miller, Enzo Charbonneau, et al.. Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages. Inorganics, 2022, 10 (7), pp.103. ⟨10.3390/inorganics10070103⟩. ⟨hal-03773676⟩
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