Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2022

Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate

Résumé

For the first time, Na3SbS4·9H2O, also known as Schlippe's salt, has been synthesized through high-energy ball milling. This innovative synthesis way allows for obtaining high purity thioantimonate nonahydrate with around 90% yield in only approximately four hours. To validate the synthesis route described herein, the crystal structure has been refined, at room temperature, through high-resolution X-ray diffraction, pair distribution function analysis and energy dispersive spectrometry. Dehydration and rehydration of the compound have also been studied by thermogravimetric analysis and differential scanning calorimetry.
Fichier principal
Vignette du fichier
article_SdS_30062022_v4.pdf (1.37 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03789446 , version 1 (27-09-2022)

Identifiants

Citer

Adam Bertrand, A. Paecklar, T. Barbier, F. Gascoin. Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate. Dalton Transactions, 2022, 51 (30), pp.11340-11345. ⟨10.1039/D2DT01520J⟩. ⟨hal-03789446⟩
51 Consultations
72 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More