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Journal Articles Dalton Transactions Year : 2022

Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate

Abstract

For the first time, Na3SbS4·9H2O, also known as Schlippe's salt, has been synthesized through high-energy ball milling. This innovative synthesis way allows for obtaining high purity thioantimonate nonahydrate with around 90% yield in only approximately four hours. To validate the synthesis route described herein, the crystal structure has been refined, at room temperature, through high-resolution X-ray diffraction, pair distribution function analysis and energy dispersive spectrometry. Dehydration and rehydration of the compound have also been studied by thermogravimetric analysis and differential scanning calorimetry.
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Dates and versions

hal-03789446 , version 1 (27-09-2022)

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Adam Bertrand, A. Paecklar, T. Barbier, F. Gascoin. Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate. Dalton Transactions, 2022, 51 (30), pp.11340-11345. ⟨10.1039/D2DT01520J⟩. ⟨hal-03789446⟩
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