Pure Rotational Spectroscopy of the CH2CN Radical Extended to the Sub-Millimeter Wave Spectral Region - CNRS - Centre national de la recherche scientifique Accéder directement au contenu
Article Dans Une Revue Journal of Physical Chemistry A Année : 2022

Pure Rotational Spectroscopy of the CH2CN Radical Extended to the Sub-Millimeter Wave Spectral Region

Résumé

We present a thorough pure rotational investigation of the CH2CN radical in its ground vibrational state. Our measurements cover the millimeter and sub-millimeter wave spectral regions (79–860 GHz) using a W-band chirped-pulse instrument and a frequency multiplication chain-based spectrometer. The radical was produced in a flow cell at room temperature by H abstraction from acetonitrile using atomic fluorine. The newly recorded transitions of CH2CN (involving N″ and Ka″ up to 42 and 8, respectively) were combined with the literature data, leading to a refinement of the spectroscopic parameters of the species using a Watson S-reduced Hamiltonian. In particular, the A rotational constant and K-dependent parameters are significantly better determined than in previous studies. The present model, which reproduces all experimental transitions to their experimental accuracy, allows for confident searches for the radical in cold to warm environments of the interstellar medium.
Fichier principal
Vignette du fichier
CH2CN_twoColumn_New.pdf (2.17 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03825293 , version 1 (22-10-2022)

Identifiants

Citer

Olivia Chitarra, Olivier Pirali, Jean-Thibaut Spaniol, Thomas Hearne, Jean-Christophe Loison, et al.. Pure Rotational Spectroscopy of the CH2CN Radical Extended to the Sub-Millimeter Wave Spectral Region. Journal of Physical Chemistry A, 2022, 126 (41), pp.7502-7513. ⟨10.1021/acs.jpca.2c04399⟩. ⟨hal-03825293⟩
63 Consultations
53 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More