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Journal Articles Organic Chemistry Frontiers Year : 2023

Playing with the cavity size of exTTF-based self-assembled cages

György Szalóki
Jennifer Bou Zeid
  • Function : Author
David Canevet
Magali Allain
Marc Sallé
Sébastien Goeb

Abstract

M4L2 metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.
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Maksym Dekhtiarenko, György Szalóki, Vincent Croué, Jennifer Bou Zeid, David Canevet, et al.. Playing with the cavity size of exTTF-based self-assembled cages. Organic Chemistry Frontiers, 2023, ⟨10.1039/D3QO00214D⟩. ⟨hal-04026661⟩
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