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Article Dans Une Revue International Journal of Chemical Kinetics Année : 2023

Comparative study of the high‐temperature auto‐ignition of cyclopentane and tetrahydrofuran

Résumé

Abstract Cyclopentane (C 5 H 10 ) and tetrahydrofuran (C 4 H 8 O) are both five‐membered ring compounds. The present study compares the auto‐ignition of cyclopentane and tetrahydrofuran in a high‐pressure shock‐tube (20 atm). Twelve different mixtures were investigated at two different fuel initial mole fractions (1% and 2%): at X fuel = 1%, three equivalence ratios, kept constant between cyclopentane and tetrahydrofuran, were studied (0.5, 1, and 2), whereas three X fuel /X O2 were investigated when X fuel = 2%. A detailed kinetic mechanism was developed to reproduce cyclopentane and tetrahydrofuran auto‐ignition. The agreement between our experimental results and the modeling is very good. This mechanism was used to explain the similarities and differences observed between cyclopentane and tetrahydrofuran auto‐ignition.
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Dates et versions

hal-04360299 , version 1 (21-12-2023)

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Hong‐quan Do, Benoîte Lefort, Zeynep Serinyel, Luis Lemoyne, Guillaume Dayma. Comparative study of the high‐temperature auto‐ignition of cyclopentane and tetrahydrofuran. International Journal of Chemical Kinetics, 2023, 56, pp.199-209. ⟨10.1002/kin.21703⟩. ⟨hal-04360299⟩
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